Bertini, F.; Glatz, M.; Stoeger, B.; Peruzzini, M.; Veiros, L. F.; Kirchner, K.; Gonsalvi, L.

Carbon Dioxide Reduction to Methanol Catalyzed by Mn(I) PNP Pincer Complexes under Mild Reaction Conditions

ACS Catal. 2019, 9, 632-639 [article]


Gonsalvi, L.

Homogeneous Catalysis and Mechanisms in Water and Biphasic Media

Catalysts 2018, 8, 543 [article] (Editorial)


Publication Cover

Armstrong, D.; Kirk, S. M.; Murphy, C.; Guerriero, A.; Peruzzini,M.; Gonsalvi,L.; Phillips, A. D.

Water-soluble Silver(I) Complexes Featuring the Hemi-labile 3,7-dimethyl-1,3,5-triaza-7-phosphabicyclo[3.3.1]nonane Ligand: Synthesis, Characterization and Antimicrobial Activity

Inorg. Chem. 2018, 57, 6309-6323 [article]


Guerriero, A.; Peruzzini, M.; Gonsalvi, L.

Ruthenium(II)-Arene Complexes of the Water-Soluble Ligand CAP as Catalysts for Homogeneous Transfer Hydrogenations in Aqueous Phase

Catalysts 2018, 8, 88 [article]


Special Issue: ECOSTBio – Spin States and Reactivity

Marcos, R.; Bertini, F.; Rinkevicius, Z.; Peruzzini, M.; Gonsalvi, L.; Ahlquist, M. S. G.

Mechanistic studies on NaHCO3 hydrogenation and HCOOH dehydrogenation reactions catalysed by a Fe(II) linear tetraphosphine complex

Chem. Eur. J. 2018, 24, 5366-5372 [article]


Cover image Coordination Chemistry Reviews

Guerriero, A.; Peruzzini, M.; Gonsalvi, L.

Coordination chemistry of 1,3,5-triaza-7-phosphatricyclo[]decane (PTA) and derivatives. Part III. Variations on a theme: novel architectures, materials and applications

Coord. Chem. Rev. 2018, 355, 328-361 [article]


Bertini, F.; Glatz, M.; Gorgas, N.; Stoeger, B.; Peruzzini, M.; Veiros, L. F.; Kirchner, K.; Gonsalvi, L.

Carbon Dioxide Hydrogenation Catalysed by Well-defined Mn(I) PNP Pincer Hydride Complexes

Chem. Sci. 2017, 8, 5024-5029 [article]


Journal Cover

Guerriero, A.; Oberhauser, W.; Riedel, T.; Peruzzini, M.; Dyson, P. J.; Gonsalvi, L.

New Class of Half-Sandwich Ruthenium(II) Arene Complexes Bearing the Water-Soluble CAP Ligand as an in Vitro Anticancer Agent

Inorg. Chem. 2017, 56, 5514-5518 [article]


Nicolas, E.; Guerriero, A.; Lyaskovskyy, V.; Peruzzini, M.; Lammertsma, K.; Gonsalvi, L.; Slootweg, J.C.

Metal-Free Reduction of Phosphine Oxides Using Polymethylhydrosiloxane

Inorganics 2016, 4, 34−41 [article], Special Issue Organophosphorus 2016


Journal Cover

Mellone, I.; Gorgas, N.; Bertini, F.; Peruzzini, M.; Kirchner, K.; Gonsalvi, L.

Selective Formic Acid Dehydrogenation Catalyzed by Fe-PNP Pincer
Complexes Based on the 2,6-Diaminopyridine Scaffold

Organometallics 2016, 35, 3344−3349 [article]


Mellone, I.; Bertini, F.; Peruzzini, M.; Gonsalvi, L.

An active, stable and recyclable Ru(II) tetraphosphine-based catalytic system for hydrogen production by selective formic acid dehydrogenation

Catal. Sci. & Technol. 2016, 6, 6504-6512 [article]


Journal Cover

Bertini, F.; Gorgas, N.; Stoeger, B.; Peruzzini, M.; Veiros, L. F.; Kirchner, K.; Gonsalvi, L.

Efficient and Mild Carbon Dioxide Hydrogenation to Formate Catalyzed by Fe(II)-Hydridocarbonyl Complexes bearing 2,6-(diaminopyridyl)diphosphine Pincer Ligands

ACS Catal. 2016, 6, 2889-2893 [article]


Kalsin, A.M.; Peganova, T. A.; Novikov, V. V.; Peruzzini, M.; Gonsalvi, L.

Cooperative effects of ruthenium micellar catalysts and added surfactants in transfer hydrogenation of ketones in water

Catal. Sci. & Technol. 2015, 5, 4458-4465 [article]


Mellone, I.; Bertini, F.; Gonsalvi, L.; Guerriero, A.; Peruzzini, M.

New Wind in Old Sails: Novel Applications of Triphos-based Transition Metal Complexes as Homogeneous Catalysts for Small Molecules and Renewables Activation

Chimia 2015, 69, 331-338. [article]


Cover image Inorganica Chimica Acta

Sordakis, K.; Guerriero, A.; Bricout, H.; Peruzzini, M.; Dyson, P. J.; Monflier, E. Hapiot, F.; Gonsalvi, L.; Laurenczy, G.

Homogenous catalytic hydrogenation of bicarbonate with water soluble biaryl phosphine ligands

Inorg. Chim. Acta 2015, 431, 132-138 [article]


Jumde, V. R.; Gonsalvi, L.; Guerriero, A.; Peruzzini, M.; Taddei, M.

A Ruthenium-Based Catalytic System for a Mild Borrowing-Hydrogen Process

Eur. J. Org. Chem. 2015, 1829-1833 [article]


Journal Cover

Bertini, F.; Mellone, I.; Ienco, A.; Peruzzini, M.; Gonsalvi, L.

Iron(II) Complexes of the Linear rac-Tetraphos-1 Ligand as Efficient Homogeneous Catalysts for Sodium Bicarbonate Hydrogenation and Formic Acid Dehydrogenation

ACS Catal. 2015, 5, 1254−1265 [article]


Potier, J.; Guerriero, A.; Menuel, S.; Monflier, E.; Peruzzini, M.; Hapiot, F.; Gonsalvi, L.

Cyclodextrins as first and second sphere ligands for Rh(I) complexes of lower-rim PTA derivatives for use as catalysts in aqueous phase hydrogenation

Catal. Commun. 2015, 63, 74-78 [article]


Talavera, M.; Bravo, J.; Gonsalvi, L.; Peruzzini, M.; Zuccaccia, C.; Bolano, S.

[IrCp*(NCMe)2(PPh2Me)][PF6]2 as Catalyst for the Meyer-Schuster Rearrangement of Aryl Propargylic Alcohols under Mild Conditions

Eur. J. Inorg. Chem. 2014, 6268-6274 [article]


Journal Cover

Guerriero, A.; Bricout, H.; Sordakis, K.; Peruzzini, M.; Monflier, E. Hapiot, F.; Laurenczy, G.; Gonsalvi, L.

Hydrogen Production by Selective Dehydrogenation of HCOOH Catalyzed by Ru-biaryl Sulfonated Phosphines in Aqueous Solution

ACS Catal. 2014, 4, 3002-3012 [article]


Caporali, M.; Gonsalvi, L.; Mirabello, V.; Ienco, A.; Manca, G.; Zanobini, F.; Peruzzini, M.

The bimetallic activation of white phosphorus by trans-[RhCl(CO)(dppm)]2 results in a tetrahedro-Rh2P2 moiety

Eur. J. Inorg. Chem. 2014, 1652-1659 [article]


Kalsin, A.M.; Peganova, T. A.; Novikov, V. V.; Zhamoityna, A. I.; Gonsalvi, L.; Peruzzini, M.

Transfer hydrogenation of ketones catalyzed by surface active ruthenium and rhodium complexes in water

Chem. Eur. J. 2014, 20, 846-854 [article]


Cover image Inorganica Chimica Acta

Tristany, M.; Laurent, R.; Dib, H.; Gonsalvi, L.; Peruzzini, M.; Majoral, J.-P.; Caminade, A.-M.

Bifunctional metallodendrimers based on AB5 derivatives of cyclotriphosphazene as core and P,N ligands as terminal functions

Inorg. Chim. Acta 2014, 409,121-126 [article]


 Journal Cover

Manca, G.; Mellone, I.; Bertini, F.; Rosi, L.; Peruzzini, M.; Mellman, D.; Junge, H.; Beller, M.; Ienco, A.; Gonsalvi, L.

Inner vs Outer-sphere Ru-catalyzed Formic Acid Dehydrogenation: A Computational Study

Organometallics 2013, 32, 7053−7064 [article]



Mirabello, V.; Caporali, M.; Gonsalvi, L.; Manca, G.; Ienco, A.; Peruzzini, M.

Stabilization of the triphosphallyl ligand eta3-P3{P(O)H} at iridium via alkaline activation of P4

Chem. Asian J. 2013, 8, 3177-3184 [article]


Caporali, M.; Guerriero, A.; Ienco, A.; Caporali, S.; Peruzzini, M.; Gonsalvi, L.

Water-soluble palladium nanoparticles stabilized by PTA and their application in biphasic catalytic hydrogenations at room temperature

Chem. Cat. Chem. 2013, 5, 2517-2526 [article]


PAC cover

Gonsalvi, L.; Guerriero, A.; Hapiot, F.; Krogstad, D. A.; Monflier, E.; Reginato, G.; Peruzzini, M.

Lower and Upper Rim-Modified PTA Derivatives: Coordination Chemistry and Applications in Catalytic Reactions in Water

Pure Appl. Chem. 2013, 85, 385-396 [article]


Journal Cover:Dalton Trans., 2013, 42, 2495-2501

Mellone, I.; Peruzzini, M.; Rosi, L.; Mellman, D.; Junge, H.; Beller, M.; Gonsalvi, L.

Formic Acid Dehydrogenation Catalysed by Ruthenium Complexes bearing the Tripodal Ligands Triphos and NP3

Dalton Trans. 2013, 42, 2495 - 2501 [article]


Alidori, S.; Heift, D.; Santiso-Quinones, G.; Benko, Z.; Gruetzmacher, H.; Caporali, M.; Gonsalvi, L.; Rossin, A.; Peruzzini, M.

Synthesis and Characterisation of terminal [Re(XCO)(CO)2(triphos)] (X = N, P): Isocyanate versus Phosphaethynolate Complexes

Chem. Eur. J. 2012, 18, 14805-14811 [article]


Journal cover: Front cover

Barbaro, P.; Gonsalvi, L.; Guerriero, A.; Liguori, F.

Facile heterogeneous catalytic hydrogenations of C=N and C=O bonds in neat water: anchoring of water-soluble metal complexes onto ion-exchange resins

Green Chem. 2012, 14, 3211-3219 [article]


Mirabello, V.; Caporali, M.; Gallo, V.; Gonsalvi, L.; Gudat, D.; Frey, W.; Ienco, A.; Latronico, M.; Mastrorilli, P.; Peruzzini, M.

Solution and Solid State Dynamics of Metal-Coordinated White Phosphorus

Chem. Eur. J. 2012, 18, 11238-11250 [article] (issue 36 cover article)


Latest Issue

Gonsalvi, L.; Peruzzini, M.

Novel Synthetic Pathways for Bis(acyl)phosphine Oxide Photoinitiators

Angew. Chem. Int. Ed. (Highlights) 2012, 51, 7895-7897 [article]


About this Journal

Servin, P.; Laurent, R.; Dib, H.; Gonsalvi, L.; Peruzzini, M.; Majoral, J.-P.; Caminade, A.-M.

Number of terminal groups versus generation of the dendrimer, which criteria influence the catalytic properties?

Tetrahedron Lett.2012, 53, 3876-3879 [article]


Caporali, M.; Gonsalvi, L.; Kagirov, R.; Mirabello, V.; Peruzzini, M.; Sinyashin, O.; Stoppioni, P.; Yakhvarov, D.

The first water-soluble tetraphosphorus ruthenium complex. Synthesis, characterization and kinetic study of its hydrolysis

J. Organomet.Chem.2012, 714, 67-73  [article]


Coletti, C.; Gonsalvi, L.; Guerriero, A.; Marvelli, L.; Peruzzini, M.; Reginato, G., Re, N.

Electron-Poor Rhenium Allenylidenes and Their Reactivity toward Phosphines: A Combined Experimental and Theoretical Study

Organometallics 2012, 31, 57-69  [article]


Krogstad, D. A.; Guerriero, A.; Ienco, A.; Manca, G.; Peruzzini, M.; Reginato, G.; Gonsalvi, L.

Imidazolyl  PTA Derivatives as Water Soluble (P,N) Ligands for Ru-catalysed Hydrogenations

Organometallics 2011, 30, 6292−6302 [article]


Mirabello, V.; Caporali, M.; Gallo, V.; Gonsalvi, L.; Ienco, A.; Latronico, M.; Mastrorilli, P.; Peruzzini, M.

Dynamic Behaviour of Ru and Ru-Pt complexes containing tetrahedron-P4 Ligand

Dalton Trans 2011, 40, 9668-9671  [article]


Six, N.; Guerriero, A.; Landy, D.; Peruzzini, M.; Gonsalvi, L.; Hapiot, F.; Monflier, E.

Supramolecularly controlled surface activity of an amphiphilic ligand. Application to biphasic hydroformylation of higher olefins

Catal. Sci. Technol. 2011, 1, 1347-1353 [article] (issue 8 cover article)


Di Credico, B.; Gonsalvi, L.; Peruzzini, M.; Reginato, G.; Rossin, A.

Design And Synthesis Of Thiazole And Thiazolidine Metallosupramolecular Networks

Phosphorus Sulfur Sil. Rel. El. 2011, 186, 1312-1315 [article]


Yakhvarov, D.; Caporali, M.; Gonsalvi, L.; Latypov, S.; Mirabello, V.; Rizvanov, I.; Sinyashin, O.; Stoppioni, P.; Peruzzini, M.

Experimental evidence of phosphine oxide generation in solution and its trapping by ruthenium complexes

Angew. Chem. Int. Ed. 2011, 50, 5370-5373  [article]


Guerriero, A.; Erlandsson, M.; Ienco, A.; Krogstad, D. A.; Peruzzini, M.; Reginato, G.; Gonsalvi, L.

Iridium(I) Complexes of Upper Rim Functionalized PTA Derivatives. Synthesis, Characterization and Use in Catalytic Hydrogenations (PTA = 1,3,5-triaza-7-phosphaadamantane)

Organometallics 2011, 30, 1874-1884  [article]


Levina, V. A.; Rossin, A.; Belkova, N. V.; Chierotti, M.; Epstein, L. M.; Filippov, O. A.; Gobetto, R.; Gonsalvi, L.; Lledos, A.;  Shubina, E. S.; Zanobini, F.; Peruzzini, M.

Acid-Base Interaction between Transition-Metal Hydrides: Dihydrogen Bonding and Dihydrogen Evolution

Angew. Chem. Int. Ed. 2011, 50, 1367-1370 [article]


Rossin, A.; Di Credico, B.; Giambastiani, G.; Gonsalvi, L.; Peruzzini, M.; Reginato, G.

Coordination Chemistry of Thiazole-Based Ligands: New Complexes Generating 3D Hydrogen-Bonded Architectures

Eur. J. Inorg. Chem. 2011, 539-548 [article]


Reginato, G.; Di Credico, B.; Gonsalvi, L.; Peruzzini, M.; Rossin, A.

Selective Synthesis of 2-Substituted  4-Carboxy Oxazoles, Thiazoles and Thiazolidines from Serine or Cysteine Amino Acids

Tetrahedron 2011, 67, 267-274  [article]


Coletti, C.; Gonsalvi, L.; Guerriero, A.; Marvelli, L.; Peruzzini, M.; Reginato, G., Re, N.

Reactivity of Rhenium Allenylidenes towards phosphines: a theoretical study

Organometallics 2010, 29, 5982-5993 [article]


Kovacs, G.; Rossin, A.; Gonsalvi, L.; Lledos, A.; Peruzzini, M.

Comparative DFT analysis of ligand and solvent effects on the mechanism of H2 activation in water mediated by half-sandwich complexes [Cp'Ru(PTA)2Cl] (Cp' = C5H5, C5Me5; PTA = 1,3,5-triaza-7-phosphaadamantane)

Organometallics 2010, 29, 5121-5131 [article]


Casini, A.; Edafe, F.; Erlandsson, M.; Gonsalvi, L.; Marrone, A.; Ciancetta, A.; Re, N.; Ienco, A.; Messori, L.; Peruzzini, M.; Dyson, P. J.

Rationalization of the inhibition activity of structurally related organometallic compounds against drug target cathepsin B by DFT analysis

Dalton Trans. 2010, 39, 5556-5563 [article] - selected as Hot Article May 2010


Rossin, A.; Gutsul, E. I.; Belkova, N. V.; Epstein, L. M.; Gonsalvi, L.; Lledos, A.; Lyssenko, K. A.; Peruzzini, M.; Shubina, E. S.; Zanobini, F.

Mechanistic study of the protonation of [(k3-P,P,P-NP3)Ir(H)3] [NP3 = N(CH2CH2PPh2)3] by HBF4 and fluorinated alcohols through combined NMR, IR and DFT techniques

Inorg. Chem. 2010, 49, 4343-4354 [article]


Caporali, M.; Gonsalvi, L.; Rossin, A.; Peruzzini, M.

P4 Activation by Late-Transition Metal Complexes

Chem. Rev. 2010, 110, 4178-4235  [article]


Ciancaleoni, G.; Bolano, S.; Bravo, J.; Peruzzini, M.;Gonsalvi, L.; Macchioni, A.

Counterion-dependent deuteration of pentamethylcyclopentadiene in water-soluble cationic Rh(III) complexes assisted by PTA

Dalton Trans. 2010,  39, 3366-3368 [article]


Bolano, S.; Plaza, M.; Bravo, J.; Castro, J.; Peruzzini, M.; Gonsalvi, L.; Ciancaleoni, G.; Macchioni, A.

New Highly Water-Soluble Rhodium Complexes Bearing 1,3,5-Triaza-7-phosphaadamantane (PTA) and/or Tris(hydroxymethyl) phosphine (THP)

Inorg. Chim. Acta 2010, 363, 509-516 [article]


Bravo, J.; Bolano, S.; Gonsalvi, L.; Peruzzini, M.

Coordination chemistry of 1,3,5-Triaza-7-phosphaadamantane (PTA) and derivatives. Part II. The quest for tailored ligands, complexes and related

Coord. Chem. Rev. 2010, 254, 555-607 [article]


Di Credico, B.; Fabrizi de Biani, F.; Gonsalvi, L.; Guerri, A.; Ienco, A.; Laschi, F.; Peruzzini, M.; Reginato, G.; Rossin, A.; Zanello, P.

Cyclopentadienyl Ruthenium(II) Complexes with Bridging Alkynylphosphine Ligands: Synthesis and Electrochemical Studies

Chem. Eur. J. 2009, 15, 11985-1998 [article]


Rossin, A.; Caporali, M.; Gonsalvi, L.; Guerri, A.; Lledos, A.; Peruzzini, M.; Zanobini, F.

Selective B-H vs. N-H bond activation in ammonia borane by [Ir(dppm)2][OTf]

Eur. J. Inorg. Chem. 2009, 3055-3059 [article]


Servin, P.; Laurent, R.; Gonsalvi, L.; Tristany, M.; Peruzzini, M.; Majoral, J.-P.; Caminade, A.-M.

Grafting of water-soluble phosphines to dendrimers and their use in catalysis: positive dendritic effects in aqueous media

Dalton Trans. 2009, 4432-4434 [article]


Legrand, F.-X.; Hapiot, F.; Tilloy,  S.;  Guerriero, A.; Peruzzini, M.; Gonsalvi, L.; Monflier, E.

Aqueous rhodium-catalyzed hydroformylation of 1-decene in the presence of randomly methylated b-cyclodextrin and 1,3,5-triaza-7-phosphaadamantane derivatives

Appl. Catal. A: Gen. 2009, 362, 62-66 [article]


Renfrew, A. K.; Phillips, A. D.; Egger, A.; Hartinger, C. G.; Bosquain, S. S.; Nazarov, A. A.; Keppler, B. K.; Gonsalvi, L.; Peruzzini, M.; Dyson, P. J.

Influence of structural variation on the anticancer activity of RAPTA-type complexes: ptn versus pta

Organometallics 2009, 28, 1165-1172 [article]


Caporali, M.; Barbaro, P.; Bolano, S.; Gonsalvi, L.; Manas Carpio, S.; Peruzzini, M.

NMR studies on the novel heterobimetallic complexes [M(dppm)(Ph2PCH2PPh2PPPP){Pt(PPh3)2}]OTf (M = Rh, Ir) derived from the stepwise activation of white phosphorus

Magn. Res. Chem. 2008, 46, S120-S125 [article]


Rossin, A; Ienco, A.; Costantino, F.; Montini, F.; Di Credico, B.; Caporali, M.; Gonsalvi, L; Fornasiero, P.; Peruzzini, M.

Crystal-to-crystal phase transition and CO2 adsorption properties of polymeric magnesium formate

Cryst. Growth Des. 2008, 8, 3302-3308 [article]


Caporali, M.; Bianchini, C.; Bolano, S.; Bosquain, S. S.; Gonsalvi, L.; Oberhauser, W.; Rossin, A.; Peruzzini, M.

Synthesis and characterisation of k1-P and k2-P,N  palladium(II) complexes of the open cage water soluble aminophosphine PTN

Inorg. Chim. Acta 2008, 361, 3017-3023 [article]


Bolano, S.; Albinati, A.; Bravo, J.; Caporali, M.; Gonsalvi, L.; Male, L.; Rodriguez-Rocha, M.; Rossin, A.; Peruzzini, M.

Synthesis and Reactivity of Rhodium(III) Pentamethylcyclopentadienyl Complexes of N-B-PTA(BH3). X-ray crystal structures of [Cp*RhCl2(N-B-PTA(BH3)] and [Cp*Rh{N-B-PTA(BH3)}(eta2-CH2=CHPh)]

J. Organomet. Chem. 2008, 693, 2397-2406 [article]


Ciclosi, M.; Dinoi, C.; Gonsalvi, L.; Peruzzini, M.; Manoury, E.; Poli, R.

Oxidation of thiophene derivatives with H2O2 in acetonitrile catalyzed by [Cp*2M2O5] (M = Mo, W): a kinetic study

Organometallics 2008, 27, 2281-2286 [article]


Caporali, M.; Barbaro, P.; Gonsalvi, L.; Ienco, A.; Yahkvarov, D.; Peruzzini, M.

Heterobimetallic cooperation mediates the transformation of white phosphorus into zwitterionic catena-phosphonium(+)diphosphenide(-) ligands

Angew. Chem. Int. Ed. 2008, 47, 3766-3768 [article] Angew. Chem. 2008, 120, 3826-3828 [article]


Yakhvarov, D.; Peruzzini, M.; Caporali, M.; Gonsalvi, L.; Midollini, S.; Orlandini, A.; Ganushevich, Y.; Sinyashin, O.

Bimetallic activation of white phosphorus

Phosphorus, Sulfur, and Silicon 2008, 183, 487-493 [article]


Bolano, S.; Ciancaleoni, G.; Bravo, J.; Gonsalvi, L.; Macchioni, A.; Peruzzini, M.

PGSE NMR studies on RAPTA derivatives: evidence for the formation of H-bonded dicationic species

Organometallics 2008, 27, 1649-1652 [article]


Erlandsson, M.; Landaeta, V. R.; Gonsalvi, L.; Peruzzini, M.; Phillips, A. D.; Dyson, P.J.; Laurenczy, G.

Methylcyclopentadienyl iridium PTA complexes and their application in catalytic water phase carbon dioxide hydrogenation (PTA = 1,3,5-triaza-7-phosphaadamantane)

Eur. J. Inorg. Chem. 2008, 620-627 [article]


Erlandsson, M.; Gonsalvi, L.; Ienco, A.; Peruzzini, M.

Diastereomerically enriched analogues of the water soluble phosphine PTA. Synthesis of phenyl-(1,3,5-triaza-7-phosphatricyclo [,7]dec-6-yl)methanol (PZA) and the Sulfide PZA(S) and X-ray Crystal Structures of the Oxide PZA(O) and [Cp*IrCl2(PZA)]

Inorg. Chem. 2008, 47, 8-10 [article]


Bolano, S.; Bravo, J.; Castro, J. A.; Rodriguez-Rocha, M.; Guedes da Silva, M. F. C.; Pombeiro, A. J. L.; Gonsalvi, L.; Peruzzini, M.

Synthesis, reactivity, x-ray crystal structures and electrochemical behavior of tris(pyrazolyl)borate ruthenium(II) complexes of PTA (PTA = 1,3,5-triaza-7-phosphaadamantane).

Eur. J. Inorg. Chem. 2007, 5523-5532 [article]


Bosquain, S. S.; Dorcier, A.; Dyson, P. J.; Erlandsson, M.; Gonsalvi, L.; Laurenczy, G.; Peruzzini, M.

Aqueous phase carbon dioxide and bicarbonate hydrogenation catalysed by cyclopentadienyl ruthenium complexes.

Appl. Organomet. Chem. 2007, 21, 947-951 [article]


Ciardi, C.; Romerosa, A., Serrano-Ruiz, M.; Gonsalvi, L.; Peruzzini, M.; Reginato, G.

Synthesis of New Enantiomerically Enriched beta-Hydroxy, gamma-Amino Phosphines by Selective Transformation of Naturally Occurring Amino Acids.

J. Org. Chem. 2007, 72, 7787 - 7789 [article]


Rossin, A.; Gonsalvi, L.; Phillips, A. D.; Maresca, O.; Lledos, A.; Peruzzini, M

Water-assisted H-H bond splitting mediated by [CpRu(PTA)2Cl] (PTA=1,3,5-triaza-7-phosphaadamantane). A DFT analysis.

Organometallics 2007, 26, 3289 - 3296 [article]


Best, J.; Wilson, J. M.; Adams, H.; Gonsalvi, L.; Peruzzini, M.; Haynes, A.

Reactivity of Rh(I) iminophosphine carbonyl complexes with methyl iodide

Organometallics 2007, 26, 1960-1965 [article]


Le Roux, E.; Malacea, R. ; Manoury, E. ; Poli, R. ; Gonsalvi, L. ; Peruzzini, M.

Highly efficient asymmetric hydrogenation of alkyl aryl ketones catalyzed by iridium complexes with chiral planar ferrocenyl phosphino-thioether ligands

Adv. Synth. Catal. 2007, 349, 309-313 [article]


Pelagatti, P.; Bacchi, A.; Balordi, M.; Caneschi, A.; Giannetto, M.; Pelizzi, C.; Gonsalvi, L.; Peruzzini, M.; Ugozzoli, F.

Ligand driven geometry switch in octahedral and trigonal bipyramidal iron complexes containing (H)PNO and PNN ligands

Eur. J. Inorg. Chem. 2007, 162-171 [article]


Gutkin, V.; Gun, J.; Prikhodchenko, P. V.; Lev, O.; Gonsalvi, L.; Peruzzini, M.; Romerosa, A.; Campos Malpartida, T.; Lidrissi, C.

Electrooxidation of ruthenium cyclopentadienyl PTA complexes in DMF: ESI-MS, cyclic voltammetry and on-line electrochemistry/ESI-MS studies

J. Electrochem. Soc. 2007, 154, F7-F15 [article]


Landaeta, V. R.; Gonsalvi, L.; Peruzzini, M.

Ruthenium catalyzed selective oxidation of aryl thiophenes using hydrogen peroxide

J. Mol. Catal. A: Chem. 2006, 257, 112-117 [article].


Journal Cover


Dorcier, A.; Ang, W. H.; Bolano, S.; Gonsalvi, L.; Juillerat-Jeannerat, L.; Laurenczy, G.; Peruzzini, M.; Phillips, A. D.; Zanobini, F.; Dyson, P. J.

In vitro evaluation of rhodium and osmium RAPTA analogues: the case for organometallic anticancer drugs not based on ruthenium

Organometallics 2006, 25, 4090-4096 [article]


Yakhvarov, D.; Barbaro, P.; Gonsalvi, L.; Manas Carpio, S.; Midollini, S.; Orlandini, A.; Peruzzini, M.; Sinyashin, O.; Zanobini, F.

A snapshot of P4 tetrahedron opening: Rh and Ir mediated bimetallic activation of white phosphorus

Angew. Chem. Int. Ed. 2006, 45, 4182-4185 [article]. Angew. Chem. 2006, 118, 4288-4291


Pelagatti, P.; Bacchi, A.; Balordi, M.; Bolano, S.; Calbiani, F.; Elviri, L.; Gonsalvi, L.; Pelizzi, C.; Peruzzini, M.; Rogolino, D.

Octahedral Ru(II) complexes with [PNO] hydrazonic ligands. Synthesis, structure, reactivity and catalytic activity in the addition of benzoic acid to alkynes

Eur. J. Inorg. Chem. 2006, 2422-2436 [article]


Journal Cover

Phillips, A. D.; Bolano, S.; Bosquain, S. S.; Daran, J.-C.; Malacea, R.; Peruzzini, M.; Poli, R.; Gonsalvi, L.

A new class of rhodium(I) k1-P and k2-P,N complexes with rigid PTN(R) ligands (PTN = 7-phospha-3-methyl-1,3,5-triazabicyclo[3.3.1]nonane)

Organometallics 2006, 25, 2189-2200. [article]


Cover image Inorganic Chemistry Communications

Bolano, S.; Albinati, A.; Bravo, J.; Gonsalvi, L.; Peruzzini, M.

Borane adducts of the water soluble phosphine PTA (PTA = 1,3,5-triaza-7-phosphaadamantane)

Inorg. Chem. Commun. 2006, 9, 360-363 [article]


Bolano, S.; Gonsalvi, L.; Barbaro, P.; Albinati, A.; Rizzato, S.; Gutsul, E.; Belkova, N.; Epstein, L.; Shubina, E.; Peruzzini, M.

Synthesis, characterization, protonation studies and X-ray crystal structure of ReH5(PPh3)2(PTA) (PTA = 1,3,5-triaza-7-phosphaadamantane)

J. Organomet. Chem. 2006, 691, 629-637 [article]


Andrieu, J.; Camus, J.-M. ; Richard, P.; Poli, R.; Gonsalvi, L.; Vizza, F.; Peruzzini, M.

Amino-phosphanes in Rh-Catalyzed Hydroformylation: Hemilabile Behavior of P,N Ligands under High CO Pressure and Catalytic Properties

Eur. J. Inorg. Chem. 2006, 51-61 [article].


Journal cover: Chemical Society Reviews

Peruzzini, M.; Gonsalvi, L.; Romerosa, A.

Coordination Chemistry and Functionalization of White Phosphorus via transition metal complexes

Chem. Soc. Rev. 2005, 34, 1038-1047 [article]


Cover image Comptes Rendus Chimie

Akbayeva, D. N.; Moneti, S.; Peruzzini, M.; Gonsalvi, L.; Ienco, A.; Vizza, F.

On the Protonation of Ruthenium-PTA Complexes in Water. X-ray crystal structure of RuCl4(PTAH)2 4H2O (PTA = 1,3,5-triaza-7-phosphaadamantane)

C. R. Chimie 2005, 8, 1491-1496. [article]


Lidrissi, C.; Romerosa, A.; Saoud, M.; Serrano-Ruiz, M.; Gonsalvi, L.; Peruzzini, M.

Stable, water soluble PTA based Ru-Ag organometallic polymers

Angew. Chem. Int. Ed. 2005, 44, 2568-2572. Angew. Chem. 2005, 117, 2624-2628 [article]


Journal Cover

Mantovani, N.; Brugnati, M.; Gonsalvi, L.; Grigiotti, E.; Laschi, F.; Marvelli, L.; Peruzzini, M.; Reginato, G.; Rossi, R.; Zanello, P.

Synthesis, characterization and electrochemical behavior of mono- and bimetallic Ru and Re allenylidenes bearing multiconjugated organic spacers

Organometallics 2005, 24, 405-418. [article]


Cover image Journal of Molecular Catalysis A: Chemical

Bolano, S.; Gonsalvi, L.; Zanobini, F.; Vizza, F.; Bertolasi, V.; Romerosa, A.; Peruzzini, M.

Water soluble ruthenium cyclopentadienyl and aminocyclopentadienyl PTA complexes as catalysts for selective hydrogenation of a,b-unsaturated olefins. (PTA = 1,3,5-triaza-7-phosphaadamantane)

J. Mol. Catal. A: Chem. 2004, 224, 61-70. [article]


Cover image Coordination Chemistry Reviews

Phillips, A. D.; Gonsalvi, L.; Romerosa, A.; Vizza, F.; Peruzzini, M.

Coordination chemistry of 1,3,5-Triaza-7-phosphaadamantane (PTA). Transition metal complexes and related catalytic, medicinal and photo-luminescent applications

Coord. Chem. Rev. 2004, 248, 955-993 [article]


Journal Cover

Ciardi, C.; Reginato, G.; Gonsalvi, L.; de los Rios, I.; Romerosa, A.; Peruzzini, M.

Ruthenium(II) pi-alkyne and vinylidene complexes derived from glycoynitols: new precursors for water soluble unsaturated carbenes

Organometallics 2004, 23, 2020-2026. [article]


Baucherel, X.; Gonsalvi, L.; Arends, I. W. C. E.; Ellwood, S.; Sheldon, R. A.

Aerobic oxidation of cycloalkanes, alcohols and ethylbenzene catalyzed by the novel carbon radical chain promoter NHS (N-hydroxy saccharin)

Adv. Synth. Catal. 2004, 346, 286-296. [article]


Gonsalvi, L.; Arends, I. W. C. E.; Moilanen, P.; Sheldon, R. A.

The effect of pH control on the selective ruthenium-catalyzed oxidation of ethers and alcohols with sodium hypochlorite

Adv. Synth. Catal. 2003, 345, 1321-1328. [article]


Journal cover: Dalton Transactions

Bianchini, C.; Gonsalvi, L.; Oberhauser, W.; Semeril, D.; Brueggeller, P; Gutmann, R.

Schulz-Flory oligomerisation of ethylene by the binuclear nickel(II) complex Ni2Cl4[cis, trans, cis-1,2,3,4-tetrakis-(diphenylphosphino)cyclobutane]

Dalton Trans. 2003, 3869-3875. [article]


Saoud, M.; Romerosa, A.; Manas Carpio, S.; Gonsalvi, L.; Peruzzini, M.

Ruthenium-catalysed selective transetherification of substituted vinyl ethers to acetals and aldehydes

Eur. J. Inorg. Chem. 2003, 1614-1619. [article]


Journal Cover

Gonsalvi, L.; Gaunt, J. A.; Adams, H.; Castro, A.; Sunley, G. J.; Haynes, A.

Quantifying steric effects of a-diimine ligands. Oxidative addition of MeI to Rh(I) and migratory insertion in Rh(III) complexes

Organometallics 2003, 22, 1047-1054. [article]


Journal cover: Chemical Communications

Akbayeva, D. N.; Gonsalvi, L.; Oberhauser, W.; Peruzzini, M.; Vizza, F.; Brueggeller, P.; Romerosa, A.; Sava, G.; Bergamo, A.

Synthesis, catalytic properties and biological activity of new water soluble ruthenium cyclopentadienyl PTA complexes [(C5R5)Ru(PTA)2Cl] (R = H, Me; PTA = 1,3,5-triaza-7-phosphaadamantane)

Chem. Commun. 2003, 264-265. [article]


Gonsalvi, L.; Adams, H.; Sunley, G. J.; Ditzel E.; Haynes, A.

Steric and electronic effects on the reactivity of Rh and Ir complexes containing P-S, P-P and P-O ligands; implications for the effects of chelate ligands in catalysis

J. Am. Chem. Soc. 2002, 124, 13597-13612. [article]


Journal Cover

Gonsalvi, L.; Arends, I. W. C. E.; Sheldon, R. A.

Selective ruthenium-catalyzed oxidation of 1,2:4,5-di-O-isopropylidene-beta-D-fructopyranose and other alcohols with NaOCl

Org. Lett. 2002, 4, 1659-1561. [article]


Journal cover: Chemical Communications

Gonsalvi, L.; Arends, I. W. C. E.; Sheldon, R. A.

Highly efficient use of NaOCl in the Ru-catalysed oxidation of aliphatic ethers to esters

Chem. Commun. 2002, 202-203. Also quoted in Chem. Br. Perspectives, April 2002. [article]


Gonsalvi, L.; Adams, H.; Sunley, G. J.; Ditzel E.; Haynes, A.

A Dramatic Steric Effect on the Rate of Migratory CO Insertion on Rhodium

J. Am. Chem. Soc. 1999, 121, 11233-11234. [article]


Cauzzi, D.; Costa, M.; Gonsalvi, L.; Pellinghelli, M. A.; Predieri, G.; Tiripicchio A.; Zanoni, R.

Anchoring rhodium(I) on thiourea-functionalized silica xerogels and silsesquioxanes. Part II. Matrix effects on the selectivity in the hydroformylation of styrene

J. Organomet. Chem. 1997, 541, 377-389. [article]




Sheldon, R. A.; Gonsalvi, L.; Arends, I. W. C. E.; Kuehnle, A.; Jost, C.; Fries, G.; Neumann, M.

Process for the oxidation of organic compounds, e.g. for production of esters from ethers, uses a liquid multi-phase ruthenium catalyst system and an oxygen atom donor and is carried out using an aqueous phase of neutral or alkaline pH

German Patent DE 10163579A1 (2003), to Degussa. [espacenet]





Gonsalvi, L.; Bertini, F.; Guerriero, A.; Mellone, I.

Hydrogen Activation in Water by Organometallic Complexes

Chapter Organometallics and Related Molecules for Energy Conversion (Ed. W.-Y. Wong), Green Chemistry and Sustainable Technology series, pages 395-419, Springer (Heidelberg-Berlin) 1st Edition, 2015

ISBN: 978-3-662-46053-5 (Print) 978-3-662-46054-2 (Online) [chapter]


Topics in Current Chemistry

Gonsalvi, L.; Guerriero, A.; Monflier, E.; Hapiot, F.; Peruzzini, M.

The Role of Metals and Ligands in Organic Hydroformylation

Top. Curr. Chem. 2013, 342, 1-47.

In Taddei, M.; Mann, A. (Eds), Hydroformylation for Organic Syntheses, Springer Berlin Heidelberg , 1st Edition. ISSN: 978-3-642-45059-4 (Online) [chapter]


Gonsalvi, L.; Peruzzini, M.

Chapter 7. Aqueous Phase Reactions Catalysed by Transition Metal Complexes of 1,3,5-triaza-7-phosphaadamantane (PTA).

In Phosphorus compounds:  advanced tools in catalysis and material sciences. Catalysis by Metal Complexes series, Vol. 37, Springer London, 1st Edition, 2011, ISBN: 978-90-481-3816-6


Gonsalvi, L.; Peruzzini, M.

1,3,5-Triaza-7-Phosphaadamantane (Unique ID RN01186)

e-EROS Encyclopedia of Reagents for Organic Synthesis, John Wiley & Sons, Ltd. 2010 [article]



Caporali, M.; Gonsalvi, L.; Zanobini, F.; Peruzzini, M.

Synthesis of the Water Soluble Bidentate (P,N) Ligand PTN(Me) [PTN(Me) = 7-Phospha-3-methyl-1,3,5-triazabicyclo[3.3.1]nonane]

Inorg. Synth. 2010, 35, 96-101. (Ed T. Rauchfuss), J. Wiley & Sons, ISBN: 978-0-471-68255-4 [book]



Bianchini, C.; Gonsalvi, L.;  Peruzzini, M.

Iridium-Catalyzed C=O hydrogenation, Chapter 4, pages 55-106

in "Iridium Complexes in Organic Synthesis"

Edited by Carmen Claver and Luis A.Oro

Wiley-VCH, Weinheim, Germany, 2008 ISBN: 978-3-527-31996-1[book]


 Peruzzini, M.; Bianchini, C.; Gonsalvi, L.

Comprehensive Organometallic Chemistry III, Chapter 7.04, pages 267-425

Edited by Robert H. Crabtree and D. Michael P. Mingos

Elsevier: Oxford 2007, ISBN: 008044590X [article]



Gonsalvi, L. (Guest Editor)

Special Issue "Homogeneous Catalysis and Mechanisms in Water and Biphasic Media"

Catalysts, MDPI Basel Switzerland, 2017, ISSN 2073-4344.


Peruzzini, M. Gonsalvi, L. (Editors)

Phosphorus compounds:  advanced tools in catalysis and material sciences

Catalysis by Metal Complexes series, Vol. 37, Springer London, 1st Edition, 2011, ISBN: 978-90-481-3816-6


Proceedings of the 9th Interdivisional Congress of Organometallic Chemistry of the Italian Society of Chemistry (COGICO-9), Florence 8-11 June 2010, (Eds B. Di Credico, L. Gonsalvi, G. Reginato), Tassinari (Firenze) 2010, ISBN 9-788887-057539


Proceedings of the 6th European Symposium on Phosphorus Chemistry (EWPC-6), Florence 26-27 March 2009, (Eds L. Gonsalvi, M. Caporali), Tassinari (Firenze) 2009, ISBN 9-788887-057492


Proceedings of the 12th International Symposium on Relations between Homogeneous and Heterogeneous Catalysis (ISHHC-XII),

Florence 18-22 July 2005, (Eds V. Dal Santo, G. Giambastiani, L. Gonsalvi, M. Guidotti), Tassinari (Firenze) 2005, ISBN 88-87057-34-6



Gonsalvi, L.; Mordini, A.; Peruzzini, M.

Organometallic Chemistry and Challenges in CO2 Activation and Utilization

Chemistry International 2019, 41, 46-48 [article].


Gonsalvi, L.; Mordini, A.; Peruzzini, M.

Conferenza Internazionale ICOMC 2018

La Chimica e l'Industria Newsletter, 2018, 5, 12-16 [article]